Cryptophanes are a class of organic supramolecular compounds studied and synthesized primarily for molecular encapsulation and recognition. One possible noteworthy application of cryptophanes is encapsulation and storage of hydrogen gas for potential use in fuel cell automobiles. Cryptophanes can also serve as containers in which organic chemists can carry out reactions that would otherwise be difficult to run under normal conditions. Due to their unique molecular recog… WebCryptophane-A, tripropargyl (1) and triallyl (2) cryptophane derivatives. Crystallization methods used for growing cryptophane-guest crystals: 12 Vapor Diffusion This method works very well for milligram quantities of cryptophane material. A solution of the cryptophane (~1 mM) is prepared using solvent S1 and placed in an open vial V1. A second
Sensitive on-chip methane detection with a cryptophane-A
WebJan 27, 2024 · The macromolecular cage cryptophane A can host methane molecules in its cavity and is thus suited as methane sensing molecule for sensors based on refractive index sensitive analytical methods like surface plasmon resonance (SPR). In this work, we assessed the methane response of different cryptophane A doped polymer membranes … WebAfter deprotection with a palladium catalyst, mono-allylated cryptophane-A (1, 2) and cryptophane-E (3) gave the new cryptophanols 4, 5 and 6, respectively, which are important key compounds for the preparation of mono-functionalized cryptophanes as well as for the design of large supramolecular hosts such as the bis-cryptophanes 7 and 8. rawhide season 1 episode 09
High Sensitive Methane Sensor With Temperature Compensation …
Webcryptophane (plural cryptophanes) ( organic chemistry ) Any of a class of large, cage-like compounds that can encapsulate smaller molecules Retrieved from " … WebDec 31, 2024 · In this article, we show that water-soluble cryptophane-222 (2), cryptophane-223 (3) and cryptophane-233 (4), bearing zero, one and two propylenedioxy linkers, … WebOct 11, 2001 · Cryptophanes are fascinating molecules and represent an important class of supramolecular hosts known to form stable inclusion complexes with neutral and cationic … rawhide season 1